Extraction of Metals - Result Question 49

49. In the electrolysis of alumina, cryolite is added to

$(1986,1 M)$

(a) lower the melting point of alumina

(b) increase the electrical conductivity

(c) minimise the anode effect

(d) remove impurities from alumina

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Answer:

Correct Answer: 49. (a, b)

Solution:

  1. Alumina $\left(Al _2 O _3\right)$ has very high melting point and it is poor conductor of electricity. Both these factors posses difficulty in electrolysis of molten alumina.

Cryolite, $Na _3 AlF _6$, when mixed with alumina, lowers melting point as well as improve electrical conductivity, hence helps in electrolysis of $Al _2 O _3$.