p-Block Elements-I - Result Question 54

25. $AlF _3$ is insoluble in anhydrous $HF$ but when little $KF$ is added to the compound it becomes soluble. On addition of $BF _3$, $AlF _3$ is precipitated. Write the balanced chemical equations.

(2004, 2M)

Show Answer

Solution:

  1. $3 KF+AlF_3 \longrightarrow BH_3+H_2$

$K _3 AlF _6+3 BF _3 \longrightarrow AlF _3 \downarrow+3 KBF _4$

ppt



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