Pblock Elementsii Result Question 13

13. Aqueous solution of $\mathrm{Na} _2 \mathrm{~S} _2 \mathrm{O} _3$ on reaction with $\mathrm{Cl} _2$ gives

(2008, 3M)

(a) $\mathrm{Na} _2 \mathrm{~S} _4 \mathrm{O} _6$

(b) $\mathrm{NaHSO} _4$

(c) $\mathrm{NaCl}$

(d) $\mathrm{NaOH}$

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Answer:

Correct Answer: 13. ( a )

Solution:

Sodium thiosulphate, $\mathrm{Na} _2 \mathrm{~S} _2 \mathrm{O} _3$ gets oxidised by chlorine water as

$\mathrm Na _2 \mathrm S _2 \mathrm O _3+4 \mathrm Cl _2+5 \mathrm H _2 \mathrm O \longrightarrow 2 \mathrm NaHSO _4+8 \mathrm HCl $

$\mathrm FeCl _3$ oxidises $\mathrm Na _2 \mathrm S _2 \mathrm O _3$ to $\mathrm Na _2 \mathrm S _4 \mathrm O _6$.



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