Pblock Elementsii Result Question 14

14. When $\mathrm{I}^-$ is oxidised by $\mathrm{KMnO} _4$ in alkaline medium, $\mathrm{I}^-$ converts into

(2004, 1M)

(a) $\mathrm{IO}^- _3$

(b) $\mathrm{I} _2$

(c) $\mathrm{IO}^- _4$

(d) $\mathrm{IO}^-$

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Answer:

Correct Answer: 14. ( a )

Solution:

$\mathrm I ^ - $ is oxidised by $\mathrm MnO _4^ - $ in alkaline medium to form $\mathrm IO _3^ - $

$2 \mathrm{KMnO}_4+\mathrm{KI}+\mathrm{H}_2\mathrm{O}\longrightarrow 2 \mathrm{KOH}+2 \mathrm{MnO}_2+\mathrm{KIO}_3$



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