Pblock Elementsii Result Question 15

15. The set with correct order of acidic strength is

(2001,1 M)

(a) $\mathrm{HClO} < \mathrm{HClO} _2 < \mathrm{HClO} _3 < \mathrm{HClO} _4$

(b) $\mathrm{HClO} _4 < \mathrm{HClO} _3 < \mathrm{HClO} _2 < \mathrm{HClO}$

(c) $\mathrm{HClO} < \mathrm{HClO} _4 < \mathrm{HClO} _3 < \mathrm{HClO} _2$

(d) $\mathrm{HClO} _4 < \mathrm{HClO} _2 < \mathrm{HClO} _3 < \mathrm{HClO}$

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Answer:

Correct Answer: 15. ( a )

Solution:

Amongst oxyacids of a given halogen, higher the oxidation number of halogen, stronger the acid. Hence,

$\mathrm{HOCl} < \mathrm{HClO} _2 < \mathrm{HClO} _3 < \mathrm{HClO} _4 .$