Pblock Elementsii Result Question 20

20. Chlorine acts as a bleaching agent only in the presence of

(1983, 1M)

(a) dry air

(b) moisture

(c) sunlight

(d) pure oxygen

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Answer:

Correct Answer: 20. ( b )

Solution:

Moist chlorine gives nascent oxygen, act as oxidising agent :

$\begin{gathered} \mathrm{Cl}_2+\mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{HCl}+\mathrm{HOCl} \\ \mathrm{HOCl} \longrightarrow \mathrm{HCl}+\underset{\text{nascent oxygen (bleaching action)}}{[\mathrm{O}]} \end{gathered}$