Pblock Elementsii Result Question 25

25. The correct statement(s) regarding,

(i) $\mathrm{HClO}$ , (ii) $\mathrm{HClO}_2$, (iii) $\mathrm{HClO}_3$ and (iv) $\mathrm{HClO}_4$ is (are)

(a) the number of $\mathrm{Cl}=\mathrm{O}$ bonds in (ii) and (iii) together is two

(b) the number of lone pair of electrons on $Cl$ in (ii) and (iii) together is three

(c) the hybridisation of $Cl$ in (iv) is $s p^3$

(d) amongst (i) to (iv), the strongest acid is (i)

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Answer:

Correct Answer: 25. ( b,c )

Solution:

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(a) Number of $\mathrm{Cl}^-=\mathrm{O}$ bonds in (ii) and (iii) together is three. Hence, wrong.

(b) Number of Lone Pair on $\mathrm{Cl}$ in (ii) and (iii) together is three. Hence, correct.

(c) In (iv), $\mathrm{Cl}$ is $s p^3$-hybridised. Hence, correct.

(d) Amongst (i) to (iv), the strongest acid is (iv). Hence, wrong.