Pblock Elementsii Result Question 3

3. Iodine reacts with concentrated $\mathrm{HNO} _3$ to yield $Y$ along with other products. The oxidation state of iodine in $Y$, is

(a) $1$

(b) $3$

(c) $7$

(d) $5$

(2019 Main, 12 Jan I)

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Answer:

Correct Answer: 3. ( d )

Solution:

  1. Iodine reacts with concentrated $\mathrm{HNO} _3$ to yield $\mathrm{HIO} _3$ along with $\mathrm{NO} _2$ and $\mathrm{H} _2 \mathrm{O}$. The reaction involved in as follows :

$\mathrm{I}_2+10 \mathrm{HNO}_3 \longrightarrow 2 \mathrm{HIO}_3+10 \mathrm{NO}_2+4 \mathrm{H}_2 \mathrm{O}$

The oxidation state of ‘I’ in $\mathrm{HIO} _3$ is 5 as calculated below :

\begin{aligned} & 1+x+3(-2)=0 \\ & x-5=0, x=+5 \\ & \end{aligned}