pBlock ElementsII 1 Question 7

7. Good reducing nature of $\mathrm{H} _{3} \mathrm{PO} _{2}$ is attributed to the presence of

(2019 Main, 9 Jan II)

(a) two $\mathrm{P}-\mathrm{H}$ bonds

(b) one $\mathrm{P}-\mathrm{H}$ bond

(c) two $\mathrm{P}-\mathrm{OH}$ bonds

(d) one $\mathrm{P}-\mathrm{OH}$ bond

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Answer:

Correct Answer: 7. (a)

Solution:

The structure of $\mathrm{H} _{3} \mathrm{PO} _{2}$ (hypophosphorous) acid is

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Due to the presence of two $\mathrm{P}-\mathrm{H}$ bonds, $\mathrm{H} _{3} \mathrm{PO} _{2}$ acts a strong reducing agent. e.g.

alt text



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