pBlock ElementsII - Result Question 87

83. Write balanced equations for the following.

(i) Phosphorus is treated with concentrated nitric acid.

(ii) Oxidation of hydrogen peroxide with potassium permanganate in acidic medium.

(iii) Manufacture of phosphoric acid from phosphorus.

(iv) Reaction of aluminium with aqueous sodium hydroxide.

$(1997,1 M \times 4=4 M)$

Show Answer

Solution:

  1. (i) $P _4+20 HNO _3 \longrightarrow 4 H _3 PO _4+20 NO _2+4 H _2 O$

(ii) $3 KMnO _4+5 H _2 O _2+3 H _2 SO _4 \longrightarrow K _2 SO _4 +2 MnSO _4+5 O _2+8 H _2 O$

(iii) $P _4+20 HNO _3 \longrightarrow 4 H _3 PO _4+20 NO _2+4 H _2 O$

(iv) $2 Al+2 NaOH+2 H _2 O \longrightarrow 2 NaAlO _2+3 H _2$



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