Periodic Classification and Periodic Properties 2 Question 34

Assertion and Reason

Read the following questions and answer as per the direction given below :

(a) Statement I is true; Statement II is true; Statement II is the correct explanation of Statement I.

(b) Statement I is true; Statement II is true; Statement II is not the correct explanation of Statement I.

(c) Statement I is true; Statement II is false.

(d) Statement I is false; Statement II is true.

34.

Statement I: F-atom has a less negative electron affinity than $\mathrm{Cl}$-atom.

Statement II: Additional electrons are repelled more effectively by $3 p$-electrons in $\mathrm{Cl}$-atom than by $2 p$-electrons in F-atom.

(1998, 2M)

Show Answer

Answer:

Correct Answer: 34. (c)

Solution:

  1. Statement I is true; Statement II is false. $\mathrm{F}$ atom has slightly lower affinity for the electron than chlorine. It is due to the reason that additional electrons are repelled more effectively by $2 p$-electrons in $\mathrm{F}$ than by $3 p$-electrons in $\mathrm{Cl}$-atom.


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