Solid State - Result Question 14

14. Sodium metal crystallises in a body centred cubic lattice with a unit cell edge of $4.29 \hspace{2mm} Å$. The radius of sodium atom is approximately

(a) $1.86 \hspace{2mm} Å$

(b) $3.22 \hspace{2mm} Å$

(c) $5.72 \hspace{2mm} Å$

(d) $0.93 \hspace{2mm} Å$

(2015 Main)

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Answer:

Correct Answer: 14. (a)

Solution:

  1. For bcc unit cell, $\sqrt{3} a=4 a$

$ \begin{aligned} r & =\frac{\sqrt{3}}{4} a \\ & =\frac{\sqrt{3}}{4} \times 4.29 \hspace{2mm} Å=1.85 \hspace{2mm} Å \\ r & =1.85 \hspace{2mm} Å \approx 1.86 \hspace{2mm} Å \end{aligned} $