Solutions and Colligative Properties - Result Question 24-1

24. Which of the following 0.1 M aqueous solution will have the lowest freezing point?

(1989, 1M)

(a) Potassium sulphate

(b) Sodium chloride

(c) Urea

(d) Glucose

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Answer:

Correct Answer: 24. (a)

Solution:

$ \begin{array}{ll} \mathrm{K}_2 \mathrm{SO}_4: & i=3 \\ \mathrm{NaCl}: & i=2 \\ \text { Urea : } & i=1 \\ \text { Glucose } & i=1 \end{array} $

Greater the value of $i$, greater the lowering in freezing point, lower will be the freezing temperature, if molarity in all cases are same. Therefore, $\mathrm{K}_2 \mathrm{SO}_4$ solution has the lowest freezing point.