Thermodynamics and Thermochemistry - Result Question 1

1. An ideal gas is allowed to expand from $1 L$ to $10 L$ against a constant external pressure of 1 bar. The work done in $kJ$ is

(2019 Main, 12 April I)

(a) $-9.0$

(b) $+10.0$

(c) $-0.9$

(d) $-2.0$

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Answer:

Correct Answer: 1. (c)

Solution:

Key Idea: Work done during isothermal expansion of an ideal gas is given by the equation.

$ W=-p _{\text {ext }}\left(V _2-V _1\right) $

According to the given conditions, the expansion is against constant external pressure. So, the work done is given by following formula;

$W =-p _{\text {ext }}\left(V _2-V _1\right) $

$ =-1 \text { bar }(10 L-1 L)=-9 L \text { bar } \quad(\because 1$ $ L $ $bar=100 $ $J) $

$ =-9 \times 100 J=-0.9 $ $kJ$



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