Thermodynamics And Thermochemistry Result Question 27

27. The standard molar heat of formation of ethane, carbon dioxide and liquid water are $-21.1,-94.1$ and $ -68.3$ kcal respectively. Calculate the standard molar heat of combustion of ethane.

(1986,2 M)

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Answer:

Correct Answer: 27. $(-372$ $ \mathrm{kcal} / \mathrm{mol})$

Solution:

$\Delta H =\Sigma \Delta H_f^{\circ} \text { (products) }-\Sigma \Delta H_f^{\circ} \text { (reactants) } $

$ =-2 \times 94.1-3 \times 68.3-(-21.1) $

$ =-372 $ $\mathrm{kcal} / \mathrm{mol}$