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JEE PYQ: Aldehydes And Ketones Question 41

Question 41 - 2019 (11 Jan Shift 1)

$p$-methylacetophenone $\xrightarrow{\text{KMnO}_4/\text{KOH}/\Delta, \text{then H}_2\text{SO}_4}$ ?

(1). (HOOC-C$_6$H$_4$-COCOOH)

(2). (OHC-C$_6$H$_4$-COOH)

(3). (HOOC-C$_6$H$_4$-COOH (terephthalic acid))

(4). (HOOC-C$_6$H$_4$-COCH$_3$)

Show Answer

Answer: (3)

Solution

KMnO$_4$/KOH/$\Delta$ oxidizes both CH$_3$ and COCH$_3$ on benzene ring to COOH groups, giving terephthalic acid.


Learning Progress: Step 41 of 49 in this series