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JEE PYQ: Aromatic Compounds Question 25

Question 25 - 2019 (12 Jan Shift 2)

m-Methoxyphenylpropene $\xrightarrow{(1) \text{Cl}_2/\text{CCl}_4; (2) \text{AlCl}_3 \text{(anhyd.)}}$ major product:

(1) Chloro-indane with MeO

(2) Linear chloro product

(3) Chloro-tetrahydronaphthalene

(4) Intramolecular Friedel-Crafts cyclized product

Show Answer

Answer: (4)

Solution

$\text{Cl}_2/\text{CCl}_4$ adds across the double bond, then intramolecular Friedel-Crafts alkylation with $\text{AlCl}_3$ gives the cyclized indane product.

Total: 25 questions (24 MCQ + 1 Integer type)


Learning Progress: Step 25 of 25 in this series