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JEE PYQ: Biomolecules And Polymers Question 39

Question 39 - 2019 (09 Apr Shift 1)

The major product of the following reaction is:

p-Cl-C$_6$H$_4$-CH$_2$CH=CH$_2$ $\xrightarrow{(1) \text{ KOH (alc.)}}$ $\xrightarrow{(2) \text{ Free radical polymerisation}}$

(1) Polymer with phenol-OH group

(2) Polymer with $\text{CH}_3$ on phenyl ring

(3) Polymer with Cl on chain

(4) Polymer with $\text{CH}_3$ group on phenyl, Cl on chain

Show Answer

Answer: (4)

Solution

Alc. KOH eliminates HCl from the allylic chloride to form a styrene derivative. Free radical polymerisation of the resulting monomer gives polystyrene derivative with $\text{CH}_3$ on the phenyl ring.


Learning Progress: Step 39 of 65 in this series