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JEE PYQ: Chemical Equilibrium Question 26

Question 26 - 2019 (11 Jan Shift 1)

Consider the reaction $\text{N}_2(g) + 3\text{H}_2(g) \rightleftharpoons 2\text{NH}_3(g)$

The equilibrium constant is $K_p$. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by (Assume $p_{\text{NH}3} \ll p{\text{total}}$):

(1) $\frac{3^{3/2} K_p^{1/2} P^2}{16}$ (2) $\frac{K_p^{1/2} P^2}{16}$ (3) $\frac{K_p^{1/2} P^2}{4}$ (4) $\frac{3^{3/2} K_p^{1/2} P^2}{4}$

Show Answer

Answer: (1) $\frac{3^{3/2} K_p^{1/2} P^2}{16}$

Solution

Since $p_{\text{NH}3} \ll P$, $P{\text{N}2} = P/4$, $P{\text{H}2} = 3P/4$. Solving gives $P{\text{NH}_3} = \frac{3^{3/2} K_p^{1/2} P^2}{16}$.


Learning Progress: Step 26 of 30 in this series