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JEE PYQ: General Organic Chemistry Question 22

Question 22 - 2020 (05 Sep Shift 1)

The increasing order of the acidity of the $\alpha$-hydrogen of the following compounds is:

(A) $\text{PhCH}_2\text{COCH}_2\text{Ph}$ (B) $\text{PhCOCH}_2\text{COPh}$ (C) $\text{CH}_3\text{COCH}_2\text{COOCH}_3$ (D) $\text{CH}_3\text{COCH}_2\text{CONMe}_2$

(1) (D) < (C) < (A) < (B)

(2) (B) < (C) < (A) < (D)

(3) (A) < (C) < (B) < (D)

(4) (C) < (A) < (B) < (D)

Show Answer

Answer: (1)

Solution

Acidity $\propto$ stability of conjugate base. Thus increasing order of acidity is D < C < A < B.


Learning Progress: Step 22 of 47 in this series