JEE PYQ: General Organic Chemistry Question 6
Question 6 - 2021 (17 Mar Shift 2)
Choose the correct statement regarding the formation of carbocations A and B given:
$\text{CH}_3\text{CH}_2\text{CH}=\text{CH}_2 + \text{HBr} \rightarrow$ “A”: $\text{CH}_3\text{CH}_2\text{CH}_2\dot{\text{C}}\text{H}_2^+$ (primary carbocation) “B”: $\text{CH}_3\text{CH}_2\dot{\text{C}}\text{H}\text{CH}_3^+$ (secondary carbocation)
(1) Carbocation B is more stable and formed relatively at faster rate
(2) Carbocation A is more stable and formed relatively at slow rate
(3) Carbocation B is more stable and formed relatively at slow rate
(4) Carbocation A is more stable and formed relatively at faster rate
Show Answer
Answer: (1)
Solution
Carbocation B is a secondary carbocation, which is more stable due to hyperconjugation and inductive effects. It is formed with faster rate due to low activation energy.