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JEE PYQ: Haloalkanes And Haloarenes Question 14

Question 14 - 2019 (09 Apr Shift 1)

The major product of the following reaction is:

2-Hydroxycyclohexanone $\xrightarrow{1.\ \text{PBr}_3}$ $\xrightarrow{2.\ \text{KOH (alc.)}}$

(1) 2-Hydroxycyclohex-2-enone

(2) Cyclohex-2-enol

(3) 2-Bromocyclohexanone derivative

(4) Cyclohex-2-enone

Show Answer

Answer: (3)

Solution

$\text{PBr}_3$ converts $-\text{OH}$ to $-\text{Br}$, then alc. KOH causes elimination. The more stable conjugated product is formed.


Learning Progress: Step 14 of 29 in this series