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The chloride that CANNOT get hydrolysed is:
(1) $\text{PbCl}_4$
(2) $\text{CCl}_4$
(3) $\text{SnCl}_4$
(4) $\text{SiCl}_4$
$\text{CCl}_4$ cannot be hydrolysed due to absence of d orbitals at carbon atom.
BETA
