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JEE PYQ: Surface Chemistry Question 32

Question 32 - 2019 (09 Jan Shift 1)

Type: MCQ

Adsorption of a gas follows Freundlich adsorption isotherm. In the given plot, $x$ is the mass of the gas adsorbed on mass $m$ of the adsorbent at pressure $p$. $\frac{x}{m}$ is proportional to:

[Graph shows $\log \frac{x}{m}$ vs $\log P$ with slope $= \frac{2}{4} = \frac{1}{2}$]

(a) $p^2$
(b) $p^{1/4}$
(c) $p^{1/2}$
(d) $p$

Show Answer

Answer: (b)

Solution

In Freundlich adsorption isotherm the extent of adsorption ($x/m$) of a gas on the surface of a solid is related to the pressure of the gas ($P$) which can be formulated as:

$\frac{x}{m} = K(P)^{1/n}$

In the given plot, the slope between $\log \frac{x}{m}$ versus $\log P = \frac{2}{4} = \frac{1}{2}$

$\therefore \frac{x}{m} \propto P^{1/2}$


Learning Progress: Step 32 of 38 in this series