JEE PYQ: Atomic Physics Question 31
Question 31 - 2020 (04 Sep Shift 1)
In the line spectra of hydrogen atom, difference between the largest and the shortest wavelengths of the Lyman series is 304 A. The corresponding difference for the Paschen series in A is: ____.
Show Answer
Answer: 10553.14
Solution
From Bohr’s formula, $\frac{1}{\lambda} = R\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)$. For Lyman series: $\frac{1}{\lambda_{min}} = R(1) \Rightarrow n_2 = \infty, n_1 = 1$. $\frac{1}{\lambda_{max}} = R\left(1 - \frac{1}{4}\right) = \frac{3R}{4}$ ($n_1 = 1, n_2 = 2$). $\lambda_{max} - \lambda_{min} = \frac{4}{3R} - \frac{1}{R} = \frac{1}{3R} = 304$ A. For Paschen series: $\lambda’{min} = R\left(\frac{1}{9}\right)$ and $\lambda’{max} = R\left(\frac{1}{9} - \frac{1}{16}\right) = \frac{7R}{144}$. $\lambda’{max} - \lambda’{min} = \frac{9 \times 16}{7R} - \frac{9}{R} = \frac{81}{7R} = \frac{81 \times 3}{7 \times 3R} = \frac{81}{7} \times 304 \times 3 = 10553.14$ A.