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JEE PYQ: Thermodynamics Question 22

Question 22 - 2020 (05 Sep Shift 1)

Three different processes that can occur in an ideal monoatomic gas are shown in the P vs V diagram. The paths are labelled as $A \to B$, $A \to C$ and $A \to D$. The change in internal energies during these processes are taken as $E_{AB}$, $E_{AC}$ and $E_{AD}$ and the work done as $W_{AB}$, $W_{AC}$ and $W_{AD}$. The correct relation between these parameters are :

(1) $E_{AB} = E_{AC} < E_{AD}$, $W_{AB} > 0$, $W_{AC} = 0$, $W_{AD} < 0$

(2) $E_{AB} = E_{AC} = E_{AD}$, $W_{AB} > 0$, $W_{AC} = 0$, $W_{AD} > 0$

(3) $E_{AB} < E_{AC} < E_{AD}$, $W_{AB} > 0$, $W_{AC} > W_{AD}$

(4) $E_{AB} > E_{AC} > E_{AD}$, $W_{AB} < W_{AC} < W_{AD}$

Show Answer

Answer: (2)

Solution

Temperature change $\Delta T$ is same for all three processes $A \to B$; $A \to C$ and $A \to D$.

$\Delta U = nC_v\Delta T =$ same

$E_{AB} = E_{AC} = E_{AD}$

Work done, $W = P \times \Delta V$

$AB \to$ volume is increasing $\Rightarrow W_{AB} > 0$

$AD \to$ volume is decreasing $\Rightarrow W_{AD} < 0$

$AC \to$ volume is constant $\Rightarrow W_{AC} = 0$


Learning Progress: Step 22 of 45 in this series