Alcohols Phenols And Ethers Ques 27

27. Which of the following will not be soluble in sodium hydrogen carbonate?

[2014]

(a) 2,4,6-trinitrophenol

(b) Benzoic acid

(c) $o$-Nitrophenol

(d) Benzenesulphonic acid

Show Answer

Solution:

  1. (c) o-nitrophenol will not be soluble in $NaHCO_3$. Due to intramolecular hydrogen bonding, hydrogen on $OH$ is strongly bound. So, it cannot be have as an acid and can not react with sodium bicarbonate.


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