Alcohols Phenols And Ethers Ques 37

37. Consider the following phenols:

The decreasing order of acidity of the above phenols is

[1999]

(a) III $>$ IV $>$ II $>$ I

(b) II $>$ I $>$ IV $>$ III

(c) I $>$ IV $>$ II $>$ III

(d) III $>$ IV $>$ I $>$ II

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Answer:

Correct Answer: 37.(a)

Solution:

(a) Electron withdrawing group $(-NO_2)$ increases the acidity while electron releasing group $(-CH_3,-H)$ decreases acidity. Also effect will be more if functional group is present at para position than ortho and meta position.