Alcohols Phenols And Ethers Ques 55
55. The major organic product in the reaction, $CH_3-O-CH(CH_3)_2+HI \to$ Product is
[2006]
(a) $ICH_2 OCH(CH_3)_2$
(b) $CH_3 OC(CH_3)_2$
(c) $CH_3 I+(CH_3)_2 CHOH$
(d) $CH_3 OH+(CH_3)_2 CHI$
Show Answer
Answer:
Correct Answer: 55.(c)
Solution:
(c) In case of unsymmetrical ethers, the site of cleavage depends on the nature of alkyl group e.g.,

The alkyl halide is always formed from the smaller alkyl group.