Amines Ques 31

31. Acetamide and ethylamine can be distinguished by reacting with

[1994]

(a) Aqueous $HCl$ and heat

(b) Aqueous $NaOH$ and heat

(c) Acidified $KMnO_4$

(d) Bromine water.

Show Answer

Solution:

  1. (b) Acetamide and ethylamine can be distinguished by heating with $NaOH$ solution.

Acetamide evolves $NH_3$ but ethylamine does not.

$ \begin{aligned} CH_3 CONH_2+NaOH \xrightarrow{\Delta} \\ CH_3 COONa+NH_3 \\ CH_3 CH_2 NH_2+NaOH \longrightarrow \text{ No reaction. } \end{aligned} $



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