Amines Ques 32

32. For carbylamine reaction, we need hot alcoholic $KOH$ and

[1992]

(a) Any primary amine and chloroform

(b) Chloroform and silver powder

(c) A primary amine and an alkyl halide

(d) A monoalkylamine and trichloromethane.

Show Answer

Solution:

  1. (a) Any primary amine means both aliphatic as well as aromatic but monoalkylamines means only $1^{\circ}$ aliphatic amines. Therefore, option (a) is correct while (d) is wrong.

$ RNH_2+CHCl_3+3 KOH \xrightarrow[\substack{RNC \\ \text{ isocyanide }}]{\longrightarrow KCl+3 H_2 O} $



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