Biomolecules Ques 66

66. Fructose reduces Tollen’s reagent due to [2010]

(a) enolisation of fructose followed by conversion to aldehyde by base

(b) asymmetric carbons

(c) primary alcoholic group

(d) secondary alcoholic group

Show Answer

Solution:

  1. (a) Fructose, a ketose as the substrate, under the alkaline medium of Tollen’s reagent, a part of fructose is transformed into glucose and mannose, both aldoses. Then these aldoses give positive silver mirror test.


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