Chemical Bonding And Molecular Structure Ques 21

21. In $NO_3{ }^{-}$ion, number of bond pair and lone pair of electrons on nitrogen atom respectively are

[2002]

(a) 2,2

(b) 3,1

(c) 1,3

(d) 4,0

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Answer:

Correct Answer: 21.(d)

Solution:

(d)

To form $NO_3^{-}$, nitrogen uses one $p$-electron for $\pi$-bond formation and two $p$-electrons for $\sigma$-bond formation. $2 s$ electrons are used for coordinate bond formation. Thus there is no lone pair on nitrogen and four bond pairs are present.