Chemical Bonding And Molecular Structure Ques 24

24. The number of anti-bonding electron pairs in $O_2^{-2}$ molecular ion on the basis of molecular orbital theory is, (Atomic number ofO is 8)

[1998]

(a) 5

(b) 2

(c) 3

(d) 4

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Answer:

Correct Answer: 24.(d)

Solution:

(d) Total no. of electrons in $O_2{ }^{2-}=16+2=18$ Distribution of electrons in molecular orbital $\sigma 1 s^2, \sigma^* 1 s^2, \sigma 2 s^2, \sigma^* 2 s^2,\sigma 2 p_x^2, \pi 2 p_y^2$

$\pi 2 p_z^2, \pi^* 2 p_x^2 \pi^* 2 p_y^2$ Anti bonding electron $=8$ (4 pairs)