Chemical Bonding And Molecular Structure Ques 5

5. Which of the following is paramagnetic?

[NEET 2013]

(a) $O_2^{-}$

(b) $CN^{-}$

(c) $NO^+$

(d) $CO$

Show Answer

Solution:

(a) Molecular orbital configuration of $O_2^-$ is

$O_2^{-}(17)=\sigma 1 s^{2}, \sigma 1 s^{*2}, \sigma 2 s^{2}, \sigma 2 s^{*2}$

$\sigma 2 p_z{ }^{2}, \pi 2 p_x{ }^{2}=\pi 2 p_y{ }^{2}, \pi^{} 2 p_x{ }^{2}=\pi^{} 2 p_y{ }^{1}$