Chemical Bonding And Molecular Structure Ques 66

66. Which of the following pairs of ions are isoelectronic and isostructural?

[2015]

(a) $ClO_3^{-}, CO_3^{2-}$

(b) $SO_3^{2-}, NO_3^{-}$

(c) $ClO_3^{-}, SO_3^{2-}$

(d) $CO_3^{2-}, SO_3^{2-}$

Show Answer

Solution:

  1. (c) $ClO_3{ }^{-}$and $SO_3{ }^{-2}$ both have same number of electrons (42) and central atom in each being $s p^{3}$ hybridised. Both are having one lone pair on central atom hence they are pyramidal.


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