Chemical Bonding And Molecular Structure Ques 70

70. Which one of the following species has plane triangular shape?

[2014]

(a) $N_3{ }^{-}$

(b) $NO_3^{-}$

(c) $NO_2^{-}$

(d) $CO_2$

Show Answer

Solution:

  1. (b) Hybridization of $NO_3^{-}=\frac{1}{2}(5+0+1-0)$ $=\frac{6}{2}=3=s p^{2}$ hence geometry is trigonal planner.

$NO_2^{-}$(nitrite ion) also has $s p^{2}$ hybridization and gives a trigonal planner geometry but because there are only two outer atoms, the molecular geometry is bent with $Ð 120^{\circ}$ bond angles.



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