Chemical Bonding And Molecular Structure Ques 77

77. Considering the state of hybridization of carbon atoms, find out the molecule among the following which is linear?

[2011]

(a) $CH_3-CH=CH-CH_3$

(b) $CH_3-C \equiv C-CH_3$

(c) $CH_2=CH-CH_2-C \equiv CH$

(d) $CH_3-CH_2-CH_2-CH_3$

Show Answer

Solution:

  1. (b) $H_3 C-C \equiv C-\stackrel{s p}{CH_3}$ linear

It is important to note that in but-2-yne, the hydrogen atoms are not linear.

$ \begin{aligned} & H \backslash s p^{3} s p^{3} s p^{3} s p^{3} X H \\ & H-C-C \equiv C-C-H \\ & H \end{aligned} $

Linear part of molecule



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