Chemical Bonding And Molecular Structure Ques 88

88. In which of the following molecules all the bonds are not equal?

[2006]

(a) $BF_3$

(c) $NF_3$

(b) $AlF_3$

(d) $ClF_3$

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Answer:

Correct Answer: 88.(d)

Solution:

(d) In $BF_3, AlF_3 & NF_3$ all fluoride atoms are symmetrically oriented with respect to central metal atom but in $ClF_3$ three fluorine atoms are arranged as follows :

Here two bonds are in equatorial plane & one bond is in axial plane.