Chemical Kinetics Ques 37

37. Half life of a first order reaction is $4 s$ and the initial concentration of the reactants is $0.12 M$. The concentration of the reactant left after $16 s$ is

[1999]

(a) $0.0075 M$

(b) $0.06 M$

(c) $0.03 M$

(d) $0.015 M$

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Answer:

Correct Answer: 37.(a)

Solution:

(a) $ t _{1 / 2}=4 s \hspace{10mm} T=16 $

$n=\frac{T}{t _{1 / 2}}=\frac{16}{4}=4 $

$A=A_o(\frac{1}{2})^{n}=0.12 \times(\frac{1}{2})^{4}=\frac{0.12}{16}=0.0075 M$

where $A_o=$ initial concentration &

$A=$ concentration left after time $t$.