Chemical Kinetics Ques 53

53. When a biochemical reaction is carried out in laboratory in the absence of enzyme then rate of reaction obtained is $10^{-6}$ times, then activation energy of reaction in the Presence of enzyme is

[2001]

(a) $\frac{6}{R T}$

(b) Different from $E_a$ obtained in laboratory

(c) $P$ is required

(d) Can’t say anything

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Answer:

Correct Answer: 53.(b)

Solution:

(b) The presence of enzyme (catalyst) increases the speed of reaction by lowering the energy barrier, i.e. a new path is followed with lower activation energy.

Here $E_T$ is the threshold energy. $E_a$ and $E _{a_1}$ is energy of activation of reaction in absence and presence of catalyst respectively.