Classification Of Elements And Periodicity In Properties Ques 17

17. Which of the following electronic configuration of an atom has the lowest ionisation enthalpy?

[2007]

(a) $1 s^{2} 2 s^{2} 2 p^{3}$

(c) $1 s^{2} 2 s^{2} 2 p^{6}$

(b) $1 s^{2} 2 s^{2} 2 p^{5} 3 s^{1}$

(d) $1 s^{2} 2 s^{2} 2 p^{5}$

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Answer:

Correct Answer: 17.(b)

Solution:

(b) $1 s^{2}, 2 s^{2}, 2 p^{5}, 3 s^{1}$ is an unstable configuration with the outermost electron in $3^{\text{rd }}$ orbit. Hence, it has lowest ionisation enthalpy.