Coordination Compounds Ques 34

34. The sum of coordination number and oxidation number of the metal $M$ in the complex $[M(en)_2(C_2 O_4)] Cl$ (where $e n$ is ethylenediamine) is:

[2015 RS]

(a) 9

(b) 6

(c) 7

(d) 8

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Answer:

Correct Answer: 34.(a)

Solution:

(a) $[M(\text{ en })_2(C_2 O_4)] Cl$

$C_2 O_4=$ bidentate ligand, carry -2 charge

en $=$ bidentate ligand, carry 0 charge

$\therefore$ M carry +3 charge; coordination number $=6$

$\therefore$ Sum $=+3+6=9$