Coordination Compounds Ques 66

66. Considering $H_2 O$ as a weak field ligand, the number of unpaired electrons in $[Mn(H_2 O)_6]^{2+}$ will be (At. no. of $M n=25$ )

[2004]

(a) three

(b) five

(c) two

(d) four

Show Answer

Solution:

  1. (b) Since $H_2 O$ is a weak ligand, it will not cause pairing of electrons in the metal ion $Mn^{2+}$. Thus electronic configuration of the metal $(Mn^{2+})$ in the complex will be

$Mn^{2+}: 1 s^{2} 2 s^{2} p^{6} 3 s^{2} 3 p^{6} 3 d^{5}$

i.e. 5 unpaired electrons.



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