Electrochemistry Ques 27

A hydrogen gas electrode is made by dipping platinum wire in a solution of $HCl$ of $pH=0$ and by passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of electrode would be ?

[NEET 2013]

(a) $0.59 V$

(b) $0.118 V$

(c) $1.18 V$

(d) $0.059 V$

Show Answer

Solution:

  1. (a) $H_2 \longrightarrow 2 H^{+}+2 e^{-}$

$1 atm \quad 10^{-10} \text{ m}$

$E _{H_2 / H^{+}}=0-\frac{0.059}{2} \log \frac{(10^{-10})^{2}}{1}$

$E _{H_2 / H^{+}}=0.00 V$



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