Equilibrium Ques 22

22. The reaction quotient $(Q)$ for the reaction

$N_2(g)+3 H_2(g) \rightleftharpoons 2 NH_3(g)$

is given by $Q=\frac{[NH_3]^{2}}{[N_2][H_2]^{3}}$. The reaction will

proceed from right to left if

[2003]

(a) $Q=0$

(b) $Q=K_c$

(c) $Q<K_c$

(d) $Q>K_c$

where $K_c$ is the equilibrium constant

Show Answer

Answer:

Correct Answer: 22.(d)

Solution:

  1. (d) For reaction to proceed from right to left

$\quad$ $\quad$ $Q$ $\quad$ > $\quad$ $K_c$

(backward) $\quad$ (forward)

i.e the reaction will be fast in backward direction i.e $\quad r_b>r_f$.

When $Q=K$, the system is at equilibrium

$Q<K_c$, reaction shift to the right from left.

$Q>K_c$, reaction proceed from right to left.