Equilibrium Ques 80

80. Equimolar solutions of the following substances were prepared separately. Which one of these will record the highest $pH$ value?

[2012]

(a) $BaCl_2$

(b) $AlCl_3$

(c) $LiCl$

(d) $BeCl_2$

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Answer:

Correct Answer: 80.(a)

Solution:

  1. (a) $.(AlCl_3, LiCl$ & $BeCl_2)$ all these solutions are acidic due to cationic hydrolysis, whereas $BaCl_2$, is salt of strong base $(Ba(OH)_2)$ and strong acid $(HCl)$, hence it will have maximum $pH$.