Hydrocarbons Ques 13

13. Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is

[2018]

(a) $CH \equiv CH$

(b) $CH_2=CH_2$

(c) $CH_4$

(d) $CH_3-CH_3$

Show Answer

Solution:

(c)

$ CH_4 \xrightarrow[h \nu]{Br_2} CH_3-Br \xrightarrow[\text{ ether }]{Na} $

$ CH_3-CH_3 $ (less than four ‘C’)