Hydrocarbons Ques 32

32. A hydrocarbon ‘$A$’ on chlorination gives ‘$B$’ which on heating with alcoholic potassium hydroxide changes into another hydrocarbon ‘$C$’. The latter decolourises Baeyer’s reagent and on ozonolysis forms formaldehyde only. ‘$A$’ is

[1998]

(a) Ethane

(b) Butane

(c) Methane

(d) Ethene

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Answer:

Correct Answer: 32.(a)

Solution:

  1. (a) Since hydrocarbon $C$ gives only $CH_2 O$, on ozonolysis, $C$ should be $CH_2=CH_2$, Hence going backward, A should be ethane. Thus, the reactions are