Hydrocarbons Ques 56

56. A compound is treated with $NaNH_2$ to give sodium salt. Identify the compound

[1993]

(a) $C_2 H_2$

(b) $C_6 H_6$

(c) $C_2 H_6$

(d) $C_2 H_4$.

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Answer:

Correct Answer: 56.(a)

Solution:

  1. (a) Only $C_2 H_2$ (acetylene) has acidic $H$-atoms and hence reacts with $NaNH_2$ to form sodium salt, i.e.,

$HC \equiv CH+NaNH_2 \longrightarrow HC \equiv CNa+NH_3$.